To fhourplay: Let me take the challenge.
You assigned me a binary string of 64 digits. The total number of possible microstates N = 2^64. You also interspersed the string with 32 "1"s. Therefore, the number of microstates in the macrostate whose total value is equal to 32 (let us identify "head" with 1 and "tail" with 0) should be n=64!/(32! x 32!). In addition, this macrostate should be most probable among all other macrostates whose total value are less than 32. Hence, finally, the complexity value (or if it is equal to the probability of forming this macrostate) is n/N.
Here I assume that the sequence does matter (meaning, 10000 is different from 00001, or 10100 is different from 00101). In other words, I assume that the symmetry of the string does not apply.
For the purpose of enhancing the clarity of our communications, let us use a shorter string, say, 5 digits. And we desire to find the complexity value of 10100. Then,
There are 32 ways of forming the string (32 microstates). There are 5!/(3! x 2!) = 10 ways (10 microstates) to form the macrostate whose total value is equal to 2. Namely,
1 1 0 0 0; 1 0 1 0 0; 1 0 0 1 0; 1 0 0 0 1; 0 1 1 0 0; 0 1 0 1 0; 0 1 0 0 1; 0 0 1 1 0; 0 0 1 0 1; 0 0 0 1 1.
Hence, the complexity value = 10/32. btw, clearly, there are 5 macrostates (if we base on the total value of a microstate to form a macrostate).
Personally, I think that this definition of disorderliness happens to coincide with that of macroscopic entropy. Let us consider, for example, a bottle of beer (m=2 kg, cv=4180 J/kg-K, A=0.0768 m^2) taken out from a refrigerator at 5 C (or 278 K; when considering entropy, we'd better use K), and placed in the living room at 298 K. Assume that the beer warming process is governed by the Newton's cooling law, i. e., J(t) = h A (298 - T(t)), where J(t) is the energy (in watts) transferred from the room to the beer bottle as a function of time (in second); h the heat transfer coefficient (assumed to be 10 W/m^2-K); A is the area of the bottle exposed to the air. We may be able to find the entropy of the universe (beer bottle + room), S_u (t), to coincide with its microscopic counterpart (complexity value, Shannon entropy, or disorderliness).
I have not had time to digest MarleysGhost's and Carroll's comments yet. But thank you all from the bottom of my heart, again.